Which property explains why transition metals and their complexes frequently act as effective heterogeneous catalysts?

Answer and explanation

Correct answer: D. Multiple oxidation states and vacant d-orbitals

  1. Step 1: Transition elements have partially filled orbitals and can adopt variable oxidation states.
  2. Step 2: This permits them to form temporary intermediate bonds with reactant molecules, lowering the activation energy barrier for heterogeneous catalysis.
Answer
Multiple oxidation states and vacant d-orbitals.
Why not the others: 'High ionic radius' is untrue as transition metal ions have relatively small radii; 'Low boiling points' is false as transition metals possess exceptionally high melting and boiling points; 'Low electronegativity' is characteristic of alkali metals, not transition catalysts.

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