Which test is used to detect the presence of primary amines through the formation of an offensive-smelling carbylamine (isocyanide)?

Answer and explanation

Correct answer: D. Carbylamine test

  1. Step 1: Both aliphatic and aromatic primary amines (R-NH2) react with chloroform (CHCl3) and alcoholic KOH on warming. Step 2. They form an extremely foul-smelling isocyanide (R-NC), known as the carbylamine test. Answer: Carbylamine test (treatment with chloroform and alcoholic KOH). Why not the others: Biuret test detects peptide bonds; Ninhydrin detects alpha-amino acids; Molisch test detects carbohydrates.

Practise more Organic Chemistry, Quantitative Analysis and Electrochemistry.

Free questions with an explanation for every one, and full timed Higher Secondary Certificate Examination (Bangladesh) mock tests.