Which of the following organic reactions represents an aldol condensation with elimination?

Answer and explanation

Correct answer: B.

  1. Step 1: In an aldol condensation, an enolate ion of an aldehyde or ketone attacks another carbonyl molecule, forming a -hydroxyaldehyde.
  2. Step 2: Upon heating, subsequent dehydration eliminates water to produce an -unsaturated carbonyl compound (crotonaldehyde: ).
  3. Step 3: The other reactions are Fischer esterification, dehydrohalogenation, and Friedel-Crafts alkylation.
Answer
2CH3CHO -> CH3-CH=CH-CHO + H2O.
Why not the others: Esterification produces an ester; alcoholic KOH produces an alkene from haloalkane; Friedel-Crafts alkylates benzene.

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