Which molecule has a lone pair on the central atom and a pyramidal shape?

Answer and explanation

Correct answer: A.

  1. Step 1: According to VSEPR theory, a trigonal pyramidal molecular geometry arises from an steric arrangement (three bonding pairs and one lone pair).
  2. Step 2: In ammonia (), the central nitrogen atom has valence electrons: form single bonds with hydrogen atoms and the remaining form one non-bonding lone pair.
  3. Step 3: The lone pair exerts greater repulsive force than bonding pairs, distorting the tetrahedral domain geometry into a trigonal pyramidal shape with bond angles of approximately .
Answer
.
Why not the others: is tetrahedral with zero lone pairs; is trigonal planar with an incomplete octet and zero lone pairs; is linear with zero lone pairs on carbon.

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