JEE Main · Chemistry

Hydrocarbons and reaction mechanisms

25 practice questions, each with the answer and an explanation.

Practise Hydrocarbons and reaction mechanisms now

Random questions from this topic, one at a time. You see the answer and the explanation straight after each one.

All 25 questions

  1. What is the major product obtained when propene is treated with in the presence of benzoyl peroxide?
  2. Which of the following carbocations is the most thermodynamically stable due to maximum hyperconjugative and resonance stabilization?
  3. Ozonolysis of an alkene followed by reductive workup with yields equal equimolar amounts of propanone (acetone) and ethanal (acetaldehyde). What is the IUPAC name of the alkene?
  4. According to Hückel's aromaticity rule, which of the following species is non-aromatic or anti-aromatic rather than aromatic?
  5. When propyne is passed into warm dilute in the presence of at (Kucherov reaction), what is the final organic product?
  6. In the conformational analysis of n-butane about the C2-C3 single bond, which conformation possesses the lowest potential energy (highest thermodynamic stability)?
  7. What is the major monobrominated product obtained from the free-radical bromination of 2-methylpropane (isobutane) with under UV light?
  8. Which of the following compounds exhibits the greatest acidic character and reacts readily with sodium amide () to release ammonia gas?
  9. In the Friedel-Crafts alkylation of benzene with 1-chloropropane in the presence of anhydrous , what is the major organic product formed?
  10. Birch reduction of benzene using sodium in liquid ammonia containing ethanol as a proton donor produces which of the following hydrocarbons?
  11. Which substituent on a benzene ring acts as a deactivating group yet directs an incoming electrophile to ortho and para positions?
  12. Addition of molecular bromine () to trans-but-2-ene in solvent proceeds via anti-addition through a cyclic bromonium ion intermediate. What is the stereochemical outcom…
  13. Which of the following alkynes will yield a red precipitate of cuprous acetylide when treated with ammoniacal cuprous chloride ()?
  14. What is the catalyst used in the Ziegler-Natta polymerization of ethene to produce high-density polyethylene (HDPE)?
  15. In the reaction of an alkene with diborane () followed by alkaline hydrogen peroxide (), the net transformation corresponds to which of the following?
  16. What is the order of reactivity of the hydrogen halides toward addition to an alkene?
  17. Heating sodium ethanoate () with solid soda-lime () in a 3:1 ratio produces which gas?
  18. Which of the following compounds will produce only a single monochloro derivative upon free-radical chlorination with ?
  19. Treatment of benzene with a mixture of concentrated and concentrated at produces nitrobenzene. What is the active electrophile in this reaction?
  20. Which of the following statements correctly explains why toluene (methylbenzene) undergoes electrophilic nitration roughly 25 times faster than benzene?
  21. When but-2-yne is hydrogenated over Lindlar's catalyst ( poisoned with lead acetate and quinoline), which product is selectively formed?
  22. What is the primary thermodynamic driving force that makes aromatic compounds resistant to addition reactions, favoring substitution reactions instead?
  23. Which of the following reactions can be used to convert an alkyl halide into an alkane containing double the number of carbon atoms?
  24. What is the IUPAC name for the hydrocarbon ?
  25. Which of the following compounds has a non-zero dipole moment despite having polar bonds?

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