26 cardsNew Zealand Scholarship

Scholarship Calculus and Physical Sciences

High-level definitions, integration techniques, mechanics laws and thermodynamic principles for New Zealand Scholarship candidates.

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What is the formula for integration by parts?
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1
What is the formula for integration by parts?
integral(u dv) = u v - integral(v * du).
2
What does L'Hopital's rule state for evaluating indeterminate limits of the form 0/0 or infinity/infinity?
lim [f(x) / g(x)] = lim [f'(x) / g'(x)], provided the derivatives exist near the point.
3
What is the general solution of the separable differential equation dy/dx = k * y?
y = y_0 e^(k x), where y_0 is the initial condition value at x = 0.
4
What is de Moivre's theorem for complex numbers in polar form?
[r (cos(theta) + isin(theta))]^n = r^n (cos(ntheta) + isin(ntheta)) = r^n e^(in*theta).
5
How is the volume of revolution about the x-axis calculated between x = a and x = b?
V = pi * integral_a^b [y(x)]^2 dx.
6
What is the definition of the dot product of two vectors u and v, and what does u . v = 0 imply?
u . v = |u| |v| cos(theta). If u . v = 0 for non-zero vectors, they are orthogonal (perpendicular).
7
What is the relationship between torque tau and angular acceleration alpha for a rigid body?
tau_net = I * alpha, where I is the rotational moment of inertia about the axis.
8
How does moment of inertia change with axis shift according to the parallel axis theorem?
I = I_cm + M * d^2, where I_cm is about the centre of mass and d is the displacement distance.
9
What is the total mechanical energy of an ideal simple harmonic oscillator of mass m, amplitude A, and spring constant k?
E = 0.5 k A^2 = 0.5 m (omega * A)^2.
10
What is the orbital speed of a satellite in circular orbit of radius r around a central body of mass M?
v = sqrt(G * M / r).
11
What is the escape velocity from the surface of a spherical planet of mass M and radius R?
v_esc = sqrt(2 G M / R).
12
What is the condition for destructive interference in a double-slit experiment?
Path difference delta x = (m + 0.5) * lambda, where m = 0, 1, 2, ...
13
What is Einstein's photoelectric equation relating photon frequency f to kinetic energy?
E_k(max) = h * f - phi, where phi is the work function of the target metal.
14
What is the de Broglie wavelength of a particle with linear momentum p?
lambda = h / p = h / (m * v).
15
What is the radius of the circular path of a particle of charge q and mass m moving with speed v perpendicular to magnetic field B?
r = m v / (q B).
16
What is Faraday's law of induction representing induced electromotive force?
emf = -d(Phi_B) / dt, where Phi_B is the magnetic flux linked through the circuit.
17
What does Lenz's law state regarding the direction of induced current?
The induced current produces a magnetic field that opposes the change in magnetic flux that generated it.
18
What is the resonant frequency of an ideal LC circuit with inductance L and capacitance C?
f_0 = 1 / (2 pi sqrt(L * C)).
19
What is the radioactive decay law connecting remaining nuclei N(t) to initial amount N_0?
N(t) = N_0 e^(-lambda t), where half-life T_half = ln(2) / lambda.
20
What is the Gibbs free energy equation relating enthalpy Delta H, entropy Delta S, and temperature T?
Delta G = Delta H - T * Delta S. A negative Delta G indicates thermodynamic spontaneity.
21
What is the relationship between standard cell potential E^0_cell and standard Gibbs energy change Delta G^0?
Delta G^0 = -n F E^0_cell, where n is moles of electrons and F is the Faraday constant.
22
How does the equilibrium constant K relate to standard Gibbs free energy change Delta G^0?
Delta G^0 = -R T ln(K).
23
What is the Henderson-Hasselbalch equation for the pH of an acid-conjugate base buffer solution?
pH = pK_a + log10([A^-] / [HA]).
24
What is the solubility product expression K_sp for calcium fluoride, CaF2?
K_sp = [Ca^2+] [F^-]^2 = (s) (2s)^2 = 4*s^3, where s is molar solubility.
25
What does the (n + 1) rule in proton NMR spectroscopy indicate about peak multiplicity?
A proton resonance splits into (n + 1) peaks, where n is the number of chemically non-equivalent protons on adjacent carbons.
26
What is Brewster's angle theta_B and what property does reflected light exhibit at this angle?
tan(theta_B) = n_2 / n_1; light reflected at Brewster's angle is 100% linearly polarized perpendicular to the plane of incidence.