What is the hybridization state of the carbon atoms in ethyne (acetylene, H-C#C-H)?

Answer and explanation

Correct answer: C. sp hybridization

  1. Step 1: Each carbon in ethyne forms one sigma bond to hydrogen and one sigma bond to the adjacent carbon, with two pi bonds.
  2. Step 2: With two sigma bonding domains and zero lone pairs, the steric number is 2.
  3. Step 3: Steric number 2 corresponds to sp hybridization with a linear 180-degree geometry.
Answer
sp hybridization.
Why not the others: 'sp2 hybridization' occurs in planar alkenes with three electron domains (120 degrees); 'sp3 hybridization' occurs in tetrahedral alkanes with four electron domains (109.5 degrees); 'sp3d hybridization' occurs in expanded octet systems such as PCl5.

Practise more Chemical Thermodynamics, Equilibrium and Organic Chemistry.

Free questions with an explanation for every one, and full timed General Education Diploma (GED Oman) mock tests.