What is the chemical name and monomer unit of natural rubber before vulcanization?

Answer and explanation

Correct answer: C. cis-1,4-Polyisoprene

  1. Step 1: Natural rubber is a natural elastomer harvested as latex from the rubber tree (Hevea brasiliensis).
  2. Step 2: Chemically, natural rubber is a linear addition polymer of isoprene (2-methylbuta-1,3-diene: ).
  3. Step 3: Crucially, all double bonds along the polymer backbone exist strictly in the cis-configuration: cis-1,4-polyisoprene.
  4. Step 4: The cis-conformation prevents close chain packing and results in coiled chains held only by weak van der Waals forces, which account for its elasticity.
Answer
cis-1,4-Polyisoprene (monomer: 2-Methylbuta-1,3-diene)
Why not the others: 'trans-1,4-Polyisoprene' is gutta-percha, a hard, non-elastic crystalline polymer; 'Polychloroprene' is synthetic neoprene rubber (monomer: chloroprene); 'Polyacrylonitrile' is a synthetic acrylic fiber (Orlon/Acrilan).

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